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Solvent-Induced Infrared Frequency Shifts in Aromatic Nitriles are Quantitatively Described by the Vibrational Stark Effect
Nitriles Spectroscopy,Fourier Transform Infrared Vibration Static Electricity Solvents
2016/5/25
The physical properties of solvents strongly affect the spectra of dissolved solutes, and this phenomenon can be exploited to gain insight into the solvent-solute interaction. The large solvatochromic...
Vibrational Stark Spectroscopy of NO Bound to Heme:Effects of Protein Electrostatic Fields on the NO Stretch Frequency
rare earth alloys X-ray diffraction crystal structure phase diagram
2016/5/23
The vibrational Stark effect measures the effect of an external electric field on the vibrational (IR) spectrum of a molecule. This technique gives quantitative information on the sensitivity of a vib...
Temperature-Dependence of the Amide-I Frequency Map for Peptides and Proteins
Amide-I Frequency map Infrared spectrum Molecular dynamics simulation
2012/4/5
In our recent work [Phys. Chem. Chem. Phys. 11, 9149 (2009)], a molecular-mechanics force field-based amide-I vibration frequency map (MM-map) for peptides and proteins was constructed. In this work, ...
High Frequency Spectroscopic Study of the Bound State of Water in PEG–H2O System during Heating from Frozen State
High Frequency Spectroscopic Study the Bound State of Water in PEG–H2O System Frozen State
2010/9/17
The bound state of water in PEG (polyethylene glycol)–H2O systems was studied by using HFS and DSC methods. Samples with the mixing ratios EO:H2O = 1:1 (a) and 1:10 (b), where EO indicates the ethylen...
Radio Frequency-Induced Plasma Polymerization of Allyl Alcohol and 1-Propanol
Plasma Polymerization Plasma Deposition Allyl Alcohol 1-Propanol XPS
2010/4/22
The effect of the composite parameters' plasma power (P)-to-monomer flow rate (f) ratio (P/f) in the plasma polymerization of allyl alcohol and 1-propanol was studied. The radio-frequency plasmas of d...