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Abstract: The Mg-vermiculite from Santa Olalla has been treated with aliphatic amides—formamide (FM), acetamide (AM) and propionamide (PM)—in aqueous solution. These treatments produce the transformat...
Abstract: This report consists of a study of l-ornithine hydrochloride-vermiculite and of benzylammonium hydrochloride-vermiculite complex. The evolution of these organo-vermiculite structures upon he...
Abstract: Continuous wave and pulsed electron paramagnetic resonance spectroscopies combined with thermal and chemical methods were used to identify and characterize V(IV), Fe(III), Mn(II) and Cr(III)...
The swelling of n-butylammonium vermiculite in water was investigated as a function of the sol concentration (r), the salt concentration (c) and the temperature (T).The interlayer spacing in the gel p...
The stacking order of a bi-ionic K/Mg vermiculite from Malawi (Nyasaland), has been determined from Weissenberg data. The sample corresponds to a K/Mg interstratified vermiculite containing 50% K laye...
X-ray diffraction, FTIR, and chemical analyses were performed on clay fractions (1? 祄, <0.1 祄), separated by means of size fractionations and high-gradient magnetic separation techniques, from a Cryor...
Abstract: Hydroxy-interlayered vermiculite (HIV) is a ubiquitous phyllosilicate in the <0.05-mm fraction of sandy soils on the U.S. southeastern coastal plain. Extensive areas of soils with abundant H...
Abstract: Clay of apparent hydrothermal origin that fills amygdales in the Granby Basaltic Tuff (Lower Jurassic) of the Connecticut Valley was analyzed and found to consist of two exceptionally well-c...
Nonexchangeable polymers in interlayers of expansible phyllosilicates influence thermal dehydration in ways not completely understood. Thermal dehydration of hydroxy-interlayered vermiculite (HIV) fro...
Hydroxyaluminosilicate (HAS) ions prepared from hydroxy-Al (HyA) ions and orthosilicic acid at different NaOH/Al molar and Si/Al atomic ratios were fixed in the interlayer spaces of vermiculite (Vt). ...
Mossbauer spectra were obtained for five Ca-exchanged nontronites and one Ca-exchanged vermiculite as the 2-layer hydrates following dehydration at 200癈. Exchange of the samples with Ca2+ and subseque...
Dealumination of vermiculite was carried out using (NH4)2SiF6 solutions. The dealuminated products were studied by high-resolution solid state 29Si and 27Al nuclear magnetic resonance. A decrease in t...
The rehydration properties and behavior of interlayer cations of Ca-, Mg-, Na-, and K-saturated homoionic saponite and vermiculite heated at various temperatures were examined and their rehydration me...
Abstract: The swelling of an n-butylammonium vermiculite in solutions of n-butylammonium chloride has been studied by neutron diffraction as a function of temperature and the concentration of the soak...
The conversion of Malawi vermiculite into K-vermiculite by treatment with bi-ionic K-Mg solutions of 1 N total ion concentration (KCl and MgCl2 mixed solutions of ionic strength equal to 0.5) was stud...

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