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【有机化学学术报告】Access Molecular Complexity by Breaking Symmetry of Dicarbonyl Compounds(图)
Molecular Complexity Breaking Symmetry Dicarbonyl Compounds
2023/6/20
【有机化学学术报告】Access Molecular Complexity by Breaking Symmetry of Dicarbonyl Compounds
Formation of α-hydroxycarbonyl and α-dicarbonyl compounds during degradation of monosaccharides
monosaccharides α-hydroxycarbonyl compounds α-dicarbonyl compounds retro-aldol reaction peroxodisulfate acetol 1,3-dihydroxyacetone glyceraldehyde glycolaldehyde acetoin 1-hydroxybutan-2-one lactaldehyde glyoxal methylglyoxal ethylglyoxal butane-2,3-dione 1-hydroxybutane-2,3-dione pentane-2,3-dione
2014/3/4
The formation of α-hydroxycarbonyl and α-dicarbonyl compounds from monosaccharides (glucose, fructose, arabinose, glyceraldehyde, and 1,3-dihydroxyacetone) was studied in three different model systems...
Manganese(III) Acetate Mediated Free Radical Cyclization of 1,3-Dicarbonyl Compounds with Sterically Hindered Olefins
Manganese(III) acetate free radical cyclization 1,3-dicarbonyl 4,5-dihydrofuran tetrahydrobenzofuran trifluoroacetyl oxidative addition
2010/4/19
The manganese(III) acetate mediated radical cyclization of dimedone 1a, 2,4-pentanedione 1b, ethyl acetoacetate 1c, 1,3-cyclohexanedione 1d and 5-phenyl-1,3-cyclohexanedione 1e with 1,1-diphenyl-1-but...
Reactions of N-Aminopyrimidine Derivatives with 1,3-Dicarbonyl Compounds
Enamine Imine 1,3-Diketone Addition reaction
2010/6/29
The reactions of 1-Amino-pyrimidine derivatives (1) and some 1,3-dicarbonyl compounds (2) were realized in the presence of p-toluensulfonic acid catalyst to give convenient enamine (3) and/or imine de...