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Solutions containing AlCl3 and Si(OH)4 (concentrations ≤ 1.5 mM with molar Si:Al ratios of 1:2, 1:1 and 3:1) and FeCl2 (0, 0.5 and 1.0 mM) were adjusted to pH 8 with Ca(OH)2, and incubated at 23°C and...
Abstract: The low temperature synthesis of iron silicate minerals with clay structures is possible at surface temperatures only under reducing conditions. Under oxidizing conditions clay minerals coul...
Biotite was altered by boiling in 0·2 M AlCl3 solution, and the products were examined by X-ray powder and single-crystal diffraction, chemical analysis and thermogravimetry. The altered material is a...

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