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Abstract: The effect of phosphate on the formation of Fe oxides from Fe(II) salts is important because phosphate is a ubiquitous anion in natural environments. For this reason, the products formed by ...
Abstract: We investigated the crystallization of ferrihydrite prepared by hydrolysis of Fe(NO3)3 solutions containing phosphate. Crystallization was studied at different pH (3–9), temperatures (298, 3...
TheuptakeofCuandCdinaqueoussolutionbyinteractionwiththesurfacesofcare- fullysynthesized?nelysizedparticlesofgoethite,lepidocrocite,mackinawite,andpyrite wasmeasuredasafunctionofinitialmetalconcentra...
Infrared (IR) spectroscopy, in combination with magnetic methods, was used to study the thermally induced transformation of synthetic lepidocrocite (γ-FeOOH) to maghemite (γ-Fe2O3). Magnetic analyses ...
Lepidocrocite samples, γ-FeOOH, containing 0–10 mole % Al-for-Fe substitution were synthesized at 15°C and pH 8 by oxidizing mixed FeCl2-AlCl3 solutions. The unit-cell parameters a, b, and c were meas...
The rate of dissolution of akaganéite in HCl increased with time over the bulk of the reaction leading to a sigmoid dissolution vs. time curve. The bulk of the dissolution of lepidocrocite could be de...
Diffractograms of lepidocrocites formed from the oxidation of Fe(II) chloride solutions at pH 7 and 25∑C showed differential line broadening with (0k0) reflections being much sharper than (hk0) or (hk...
The presence of Al hydroxy species in solution during the synthesis of lepidocrocite had been previously found to influence the reaction towards goethite formation. However, under certain conditions, ...
Lepidocrocite was identified associated with mica particles and in the clay fraction of two well-drained Ontario soils developed on a granite and a granite-gneiss. The occurrence of lepidocrocite is r...
The mechanism of the transformation of lepidocrocite (γFeOOH) to goethite (αFeOOH) has previously been established and the effect of silicate on the transformation was investigated. Rather than comple...
The conversion of lepidocrocite (γFeOOH) to its more stable polymorph, goethite (αFeOOH) was followed by observing changes in crystal morphology, oxalate solubility, surface area and X-ray diffraction...

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