搜索结果: 1-14 共查到“大气化学 the gas phase”相关记录14条 . 查询时间(0.099 秒)
Formation of secondary aerosols over Europe: comparison of two gas-phase chemical mechanisms
secondary aerosols Europe two gas-phase chemical mechanisms
2011/2/24
The impact of two recent gas-phase chemical kinetic mechanisms (CB05 and RACM2) on the formation of secondary inorganic and organic aerosols is compared for simulations of PM2.5 over Europe between 15...
Spectroscopic studies of molecular iodine emitted into the gas phase by seaweed
Spectroscopic studies molecular iodine the gas phase
2010/8/16
Time profiles of molecular iodine emissions from seven species of seaweed have been measured at high time resolution (7.5 s) by direct spectroscopic quantification of the gas phase I2 using broadband ...
Modelling the reversible uptake of chemical species in the gas phase by ice particles formed in a convective cloud
chemical species the gas phase ice particles a convective cloud
2010/8/13
The present paper is a preliminary study preparing the introduction of reversible trace gas uptake by ice particles into a 3-D cloud resolving model. For this a 3-D simulation of a tropical deep conve...
Comparison of tropospheric gas-phase chemistry schemes for use within global models
tropospheric gas-phase chemistry schemes global models
2009/3/13
Methane and ozone are two important climate gases with significant tropospheric chemistry. Within chemistry-climate and transport models this chemistry is simplified for computational expediency. We c...
Organic nitrate and secondary organic aerosol yield from NO3 oxidation of β-pinene evaluated using a gas-phase kinetics/aerosol partitioning model
Organic nitrate secondary organic aerosol gas-phase kinetics/aerosol partitioning model
2009/3/13
The yields of organic nitrates and of secondary organic aerosol (SOA) particle formation were measured for the reaction NO3+β-pinene under dry and humid conditions in the atmosphere simulation chamber...
Internal mixing of the organic aerosol by gas phase diffusion of semivolatile organic compounds
organic aerosol gas phase diffusion semivolatile organic compounds
2009/3/10
This paper shows that most of the so far identified constituents of the tropospheric organic particulate matter belong to a semivolatile fraction for which gas phase diffusion in the lower troposphere...
Evaluated kinetic and photochemical data for atmospheric chemistry: Volume I - gas phase reactions of Ox, HOx, NOx and SOx species
Evaluated kinetic atmospheric chemistry gas phase reactions
2009/3/5
This article, the first in the series, presents kinetic and photochemical data evaluated by the IUPAC Subcommittee on GasKinetic Data Evaluation for Atmospheric Chemistry. It covers the gas phase and ...
Kinetic study of the gas-phase reaction of atomic chlorine with a series of aldehydes
Kinetic study gas-phase reaction atomic chlorine aldehydes
2009/2/19
The reactions of Cl atoms with a series of unsaturated aldehydes have been investigated for the first time using a relative method. In order to obtain additional information for a qualitative structur...
Modelling the evolution of organic carbon during its gas-phase tropospheric oxidation: development of an explicit model based on a self generating approach
organic carbon gas-phase tropospheric oxidation explicit model self generating approach
2009/2/17
Organic compounds emitted in the atmosphere are oxidized in complex reaction sequences that produce a myriad of intermediates. Although the cumulative importance of these organic intermediates is wide...
Kinetic modeling of secondary organic aerosol formation: effects of particle- and gas-phase reactions of semivolatile products
Kinetic modeling secondary organic aerosol formation semivolatile products
2008/12/16
The distinguishing mechanism of formation of secondary organic aerosol (SOA) is the partitioning of semivolatile hydrocarbon oxidation products between the gas and aerosol phases. While SOA formation ...
Evaluated kinetic and photochemical data for atmospheric chemistry: Volume III – gas phase reactions of inorganic halogens
kinetic photochemical data atmospheric chemistry inorganic halogens
2008/12/2
This article, the third in the series, presents kinetic and photochemical data evaluated by the IUPAC Subcommittee on Gas Kinetic Data Evaluation for Atmospheric Chemistry. It covers the gas phase and...
Measurement and interpretation of gas phase formaldehyde concentrations obtained during the CHABLIS campaign in coastal Antarctica
formaldehyde CHABLIS coastal Antarctica
2008/11/13
Gas phase formaldehyde concentrations were measured during the 2004–2005 CHABLIS campaign at Halley research station, Antarctica. Data coverage span from May 2004 through to January 2005, thus capturi...
Predicting arene rate coefficients with respect to hydroxyl and other free radicals in the gas-phase: a simple and effective method using a single topological descriptor
arene hydroxyl free radicals topological descriptor
2008/11/12
The reactivity of aromatic compounds is of great relevance to pure and applied chemical disciplines, yet existing methods for estimating gas-phase rate coefficients for their reactions with free radic...
Oligomer formation during gas-phase ozonolysis of small alkenes and enol ethers: new evidence for the central role of the Criegee Intermediate as oligomer chain unit
oligomer formation gas-phase ozonolysis small alkenes enol ethers
2008/11/7
An important fraction of secondary organic aerosol (SOA) formed by atmospheric oxidation of diverse volatile organic compounds (VOC) has recently been shown to consist of high-molecular weight oligome...