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2,2'-Binaphthylene phosphorochloridite (BINOL-PCl) as a bulky and efficient reagent for the conversion of primary and secondary alcohols into iodides, and tertiary alcohols stereo- and/or regioselectively into olefin(s)
Alkyl iodide 2,2'-dihydroxy-1,1'-dinaphthalene (BINOL) 2,2'-binaphthylene phosphorochloridite (BINOL-PCl) stereoselective anti-E2 elimination reaction heavy atom effect
2010/4/8
Primary and secondary alcohols were transformed in high yield to corresponding iodides by 4-chloro-3,5-dioxaphosphacyclohepta [2,1-a; 3,4-a'] dinaphthalene (BINOL-PCl) at room temperature. The tertiar...