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Structural Fe3+ in Natural Kaolinites: New Insights from Electron Paramagnetic Resonance Spectra Fitting at X and Q-Band Frequencies
Dickite Disorder EPR Fe3+ Kaolinite
2011/12/7
Abstract: Structural Fe3+ in kaolinites and dickites covering a broad range of disorder was investigated using electron paramagnetic resonance (EPR) spectroscopy at both the X and Q-band frequencies. ...
Nature of Structural Disorder in Natural Kaolinites: A New Model Based on Computer Simulation of Powder Diffraction Data and Electrostatic Energy Calculation
Energy calculation Kaolinite Layer disorder XRPD simulation
2011/12/28
A new model for the description of the structural disorder in natural kaolinite materials is proposed, based on the stacking of two 1:1 layers and their enantiomorphs, and encompassing previously prop...
Nature and Stability of Radiation-Induced Defects in Natural Kaolinites: New Results and a Reappraisal of Published Works
EPR Kaolinite Radiation induced defects RID
2011/12/29
A new appraisal of radiation-induced defects (RID) in natural kaolinite, i.e., positive trapped holes on oxygen atoms, has been undertaken using Q-band EPR spectra, recorded at 93 K, of irradiated ann...
Determination of Structural Defects in Phyllosilicates by X-Ray Powder Diffraction—II. Nature and Proportion of Defects in Natural Kaolinites
Structural Defects Phyllosilicates X-Ray Powder Diffraction Natural Kaolinites
2012/2/13
Until now, the different attempts to describe the defects of kaolinites were based on the ideas that (i) the hkl reflections with k = 3n are Bragg reflections, while (ii) the hkl reflections with k ≠ ...